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论文类型：期刊论文

发表时间：2018-01-01

发表刊物：SUPRAMOLECULAR CHEMISTRY

收录刊物：SCIE、Scopus

卷号：30

期号：1

页面范围：72-79

ISSN号：1061-0278

关键字：Cross-linked; supramolecular polymer; pillararene; FRET

摘要：Cross-linked supramolecular polymers generally show distinct mechanical properties with intriguing functions, which have become one of the hot research topics in recent years. However, the cross-linked supramolecular polymers functionalised with fluorescence resonance energy transfer (FRET) properties have been rarely reported yet. Herein, a new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully. The oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as a host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerisation and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV-vis and SEM.
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   A new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully, the oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as both host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerization and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV-vis and SEM.