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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：西部校区化工综合楼A403
联系方式：0411-84986065
电子邮箱：ninggl@dlut.edu.cn
Synthesis, structure, magnetism and antibacterial properties of a 2-D nickel(II) metal-organic framework based on 3-nitrophthalic acid and 4,4 '-bipyridine
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论文类型：期刊论文
发表时间：2014-01-01
发表刊物：JOURNAL OF COORDINATION CHEMISTRY
收录刊物：SCIE、Scopus
卷号：67
期号：7
页面范围：1133-1140
ISSN号：0095-8972
关键字：Metal-organic framework; Nickel; Dinuclear building blocks; Magnetic property; Antibacterial activity
摘要：A 2-D nickel(II) mixed-ligand metal-organic framework [Ni(NPTA)(4,4'-bipy)(H2O)](n) (1) was synthesized by reaction of 3-nitrophthalic acid (H(2)NPTA) and 4,4'-bipyridine (4,4'-bipy) with Ni(II) under hydrothermal condition and characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound 1 possesses a 2-D layer structure constructed from dinuclear nickel(II) building blocks in which two crystallographically equivalent Ni ions are bridged by two NPTA ligands. Furthermore, the layers are connected into 3-D supramolecular network by hydrogen bonds. The magnetism and antibacterial activity of 1 were investigated.