宁桂玲

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:化学工艺. 功能材料化学与化工. 无机化学

办公地点:西部校区化工综合楼A403

联系方式:0411-84986065

电子邮箱:ninggl@dlut.edu.cn

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A new principle for selective sensing cyanide anions based on 2-hydroxy-naphthaldeazine compound

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论文类型:期刊论文

发表时间:2013-02-01

发表刊物:SENSORS AND ACTUATORS B-CHEMICAL

收录刊物:SCIE、EI

卷号:177

页面范围:322-326

ISSN号:0925-4005

关键字:"Turn-on" fluorescence; 2-Hydroxy-naphthaldeazine; Cyanide anions; Hydrogen bonds; Aggregation-induced emission

摘要:2-Hydroxy-naphthaldeazine (HNA), synthesized readily via one-step condensation from 3-hydroxy-2-naphthaldehyde and hydrazine monohydrate, behaves as "turn-on" fluorescent sensing of CN-selectively. The sensing mechanism was ascribed to the dual influence of hydrogen bonds and aggregation-induced emission, coming from the interactions of HNA and CN-. The speculation was partially supported by fluorescence emission spectra, UV-vis spectrum, H-1 NMR titration experiments and further particle size analysis. (c) 2012 Elsevier B.V. All rights reserved.