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论文类型：期刊论文

发表时间：2012-07-25

发表刊物：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

收录刊物：SCIE、ISTIC、CSCD、Scopus

卷号：28

期号：4

页面范围：555-558

ISSN号：1005-9040

关键字：Cu-3(BTC)(2)(HKUST-1); Metal-organic framework; Coordination modulation method

摘要：A simple and fast route for the synthesis of metal-organic framework(MOF) particles was presented. Cu-3(BTC)(2)(HKUST-1, BTC=1,3,5-benzenetricarboxylate), one of the most well-known MOFs, was synthesized at room temperature via coordination modulation method. By adding different modulators(monocarboxylic acids) into the reaction system, the morphologies of HKUST-1 crystals were tuned from nano spheres to micro octahedrons at room temperature without any complex equipment. X-Ray diffractions and gas sorption measurements revealed highly crystalline particles with large Brunauer-Emmett-Teller(BET) surface areas(1116-1273 m(2)/g) and total pore volumes(0.62-0.73 cm(3)/g). The significantly small particle sizes and high capacity of gas sorption are considered advantageous for envisaged application in practical industrial process.