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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：西部校区化工综合楼A403
联系方式：0411-84986065
电子邮箱：ninggl@dlut.edu.cn
Synthesis and characterization of a new framework cobalt phosphate with one-dimensional channel, Co-3(H2O)(4)(PO4)(2)
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论文类型：期刊论文
发表时间：2008-01-01
发表刊物：ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
收录刊物：SCIE
卷号：634
期号：6-7
页面范围：1145-1148
ISSN号：0044-2313
关键字：cobalt; cobalt phosphate; crystal structure; hydrothermal synthesis
摘要：A new cobalt phosphate, Co-3(H2O)(4)(PO4)(2) (1) has been synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. Crystal data for 1: orthorhombic system, Pnma, a = 10. 582(2) angstrom, b = 18.289(4) angstrom, c = 5.0236(10) angstrom, V = 972.2(3) angstrom(3), Z = 4. The compound displays complex threedimensional framework containing one-dimensional 8-membered ring channels. In this crystal structure, CoO4 and PO4 tetrahedra connect each other by sharing-vertex to form the infinite two-dimensional sheet which contains the edge-sharing four ring chain and double zig-zag chain, then these sheets are pillared by CoO2(H2O)(4) octahedra.