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论文类型：期刊论文

发表时间：2019-08-07

发表刊物：NEW JOURNAL OF CHEMISTRY

收录刊物：SCIE

卷号：43

期号：29

页面范围：11517-11523

ISSN号：1144-0546

摘要：In this study, a novel flexible and robust dual-network supramolecular elastic film with solvent resistance and brilliant structural colors was prepared by combining a Zn2+-crosslinked supramolecular elastic film with polystyrene@silica (PS@SiO2) colloidal crystals. This structurally colored supramolecular elastic material consisted of a covalent support network formed by three different monomers and a Zn2+-crosslinked polyacrylic acid (PAA) coordination network, which provided high mechanical strength and flexibility. The tensile and compression stress of this structural color reached 3.26 MPa at a strain of 187% and a pressure of 300 N. The reflectance wavelength of the structural color film remained unchanged after loading-unloading cycles and compression cycles. The structural color film could be bent and unfolded without heating or the application of an external stimulus. Moreover, the structural color film exhibited resistance to solvents in saturated organic vapors and remained color invariant.