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Improvement of quantitative analysis of molybdenum element using PLS-based approaches for laser-induced breakdown spectroscopy in various pressure environments
发表时间:2020-06-02 点击次数:
论文类型: 期刊论文
第一作者: Liu, Jiamin
通讯作者: Ding, HB (reprint author), Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Sch Phys, Dalian 116024, Peoples R China.
合写作者: Wu, Ding,Fu, Cailong,Hai, Ran,Yu, Xiao,Sun, Liying,Ding, Hongbin
发表时间: 2019-03-01
发表刊物: PLASMA SCIENCE & TECHNOLOGY
收录刊物: SCIE、EI
文献类型: J
卷号: 21
期号: 3
ISSN号: 1009-0630
关键字: laser induced breakdown spectroscopy; molybdenum; vacuum; normalization; partial least squares method; quantitative analysis
摘要: An experimental setup has been designed and realized in order to optimize the characteristics of laser-induced breakdown spectroscopy system working in various pressure environments. An approach combined the normalization methods with the partial least squares (PLS) method are developed for quantitative analysis of molybdenum (Mo) element in the multi-component alloy, which is the first wall material in the Experimental Advanced Superconducting Tokamak. In this study, the different spectral normalization methods (total spectral area normalization, background normalization, and reference line normalization) are investigated for reducing the uncertainty and improving the accuracy of spectral measurement. The results indicates that the approach of PLS based on inter-element interference is significantly better than the conventional PLS methods as well as the univariate linear methods in the various pressure for molybdenum element analysis.
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