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    齐民

    • 教授     博士生导师   硕士生导师
    • 主要任职:Professor
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:材料科学与工程学院
    • 学科:材料学. 生物医学工程
    • 办公地点:材料学院222房间
    • 联系方式:84708441
    • 电子邮箱:minqi@dlut.edu.cn

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    苯胺-SrTi(C2O4)2颗粒制备及其电流变性能

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    发表时间:2014-01-01

    发表刊物:复合材料学报

    期号:1

    页面范围:81-87

    ISSN号:1000-3851

    摘要:The aniline-strontium titanyl oxalate (aniline-SrTi(C2O4)2) particles were prepared by a precipitation method. FTIR patterns show that aniline has been added to the surface of the SrTi(C2O4)2 particles. XRD patterns indicate that the particles are amorphous structure with a little of crystallization. The morphology of the particles was observed by SEM, the results of which indicate that with the increase of the molar ratio of aniline toTi atoms, naniline/nTi, the smorphology of aniline-SrTi(C2O4)2 particles change from approximate globular (naniline/nTi=0) to a polyhedron shape (naniline/nTi=2), and then a mixure consists of rod and cluster shaped particles (naniline/nTi=3). The electrorheological (ER) fluids were prepared with 66.7% mass fraction of aniline-SrTi(C2O4)2 particles with different aniline contentand tested. The experimental results indicate that the ER fluid prepared by the particles with a molar ratio of naniline/nTi=2 present the largest field-induced shear stress, yield stress and leak current density. The aniline controls the particle morphology during the preparation of the particles, and acts as polar molecules in the ER fluids system. The influence of the aniline on properties of the ER fluids is a combined effect of the two roles.

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