Xuehua Ruan
Professor Supervisor of Doctorate Candidates Supervisor of Master's Candidates
Title : 辽宁省工业VOCs综合治理及利用专业技术创新中心副主任
Gender:Male
Alma Mater:大连理工大学
Degree:Doctoral Degree
School/Department:化工海洋与生命学院
Discipline:Chemical Engineering. Membrane Science and Technology. Water Science and Technology
Business Address:盘锦校区D01-316A
E-Mail:xuehuaruan@dlut.edu.cn
Hits:
Indexed by:期刊论文
Date of Publication:2016-06-22
Journal:SEPARATION AND PURIFICATION TECHNOLOGY
Included Journals:SCIE、EI
Volume:166
Page Number:171-180
ISSN No.:1383-5866
Key Words:CO2; Poly(ether-b-amide); MMMs; Gas separation; Functionalized graphene oxide
Abstract:Mixed matrix membranes (MMMs) were composed of imidazole functionalized graphene oxide (ImGO), a CO2-philic nano-sheet inorganic material, and poly(ether-b-amide) (PEBAX) for CO2 capture. MMM doped with 0.8 wt.% ImGO exhibits the best CO2 separation performance, which shows the CO2/N-2 selectivity up to 105.5 combined with CO2 permeability of 76.2 Barrer (1 Barrer = 10(-10) cm(3)(STP) cm cm(-2) s(-1) cmHg(-1)), surpassing the Robeson Upper Bound of 2008. The selectivity of MMM for CO2/N-2 increases by 46.0% compared to the Pristine PEBAX due to the interaction between CO2 and imidazole groups. With the increase of feed pressure, CO2 permeability increases significantly because of its higher solubility in polymer matrix and plasticization. It is effective to separation CO2 from N-2 at lower temperature for MMMs because the apparent activation energy of the N-2 permeation process in ImGO/PEBAX MMMs is much higher than that of CO2. Tg of MMMs are increased gradually because the polymer chain mobility is restricted by the presence of ImGO and a rigidified interface generates between polymer and filler. The mechanical properties have been significantly enhanced by the ImGO sheet as expected because of the presence of H-bonding. Having distinct improvement of CO2 separation performance, the ImGO/PEBAX MMMs indicates promising applications in CO2 capture processes. (C) 2016 Elsevier B.V. All rights reserved.
阮雪华,教授,博士生导师,国家级青年人才。
辽宁省工业VOCs综合治理及利用工程技术研究中心副主任。
长期从事新型高效分离膜及其工业化过程研究,包括膜材料设计合成、特种分离膜研制及规模化生产、膜组件高精度离散数值计算以及多源复杂分离过程优化设计等具体方向,是科技部“新型高效过程耦合强化”创新团队和基金委“气体分离和新能源膜与膜工程”创新研究群体的年轻骨干,负责国家自然科学基金项目3项,国家重点研发计划国际合作项目子课题1项,博士后科学基金面上一等资助1项,参与国家自然科学基金重大科研仪器研制项目、重点项目、面上项目等6项,在AIChE J., Chem. Eng. Sci.和J. Membr. Sci.等化工领域权威期刊发表SCI论文110余篇,申请国家发明专利100余项,获授权60项,研发的膜产品和工艺技术已经在中石化镇海炼化、胜利油田、西北油田、中石油辽河石化、辽阳石化和大连石化等企业成功实施20余项,荣获国家科学技术进步二等奖2次(膜法高效回收与减排化工行业挥发性有机气体,第三完成人,2018年;含烃石化尾气梯级耦合膜分离技术研发与工业应用,第四完成人,2010年)、侯德榜化工科技青年奖1次、日内瓦国际发明展特别嘉许金奖1次、中国石油和化学工业联合会/协会科技进步一等奖2次、中国专利优秀奖1次,2019年入选辽宁省兴辽英才计划青年拔尖人才,2020年被聘为《膜科学与技术》通讯编委,入选中国化工学会化工过程强化专委会青委会委员,2021年被聘为中文EI期刊《化工进展》编委。
已发表SCI学术论文
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[27] A novel imidazolium-based amphoteric membrane for high-performance vanadium redox flow battery, X Yan, C Zhang, Y Dai, W Zheng, X Ruan, G He, Journal of Membrane Science, 2017, 544, 98-107
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[25] Enhancing mechanical stability and uniformity of 2-D continuous ZIF-8 membranes by Zn (II)-doped polydopamine modification, X Ruan, X Zhang, X Liao, X Jiang, Y Dai, X Yan, G He, Journal of Membrane Science, 2017, 541, 101-107
[24] Polyethyleneimine‐grafted membranes for simultaneously adsorbing heavy metal ions and rejecting suspended particles in wastewater, X Ruan, Y Xu, X Liao, G He, X Yan, Y Dai, N Zhang, L Du, AIChE Journal, 2017, 63, 4541-4548
[23] Improvement of alkaline stability for hydroxide exchange membranes by the interactions between strongly polar nitrile groups and functional cations, X Yan, R Deng, Y Pan, X Xu, I El Hamouti, X Ruan, X Wu, C Hao, G He, Journal of Membrane Science, 2017, 533, 121-129
[22] Formation mechanism of the spiral-like structure of a hydrogen bond network confined in a fluorinated nanochannel: a molecular dynamics simulation, N Zhang, Y Song, J Huo, Y Li, Z Liu, J Bao, S Chen, X Ruan, G He, The Journal of Physical Chemistry C, 2017, 121 (25), 13840-13847
[21] Modeling and simulation of mitigating membrane fouling under a baffle-filled turbulent flow with permeate boundary, W Zhang, X Ruan, Y Ma, X Jiang, W Zheng, Y Liu, G He, Separation and Purification Technology, 2017, 179, 13-24
[20] Molecular dynamics study of confined structure and diffusion of hydrated proton in Hyfion® perfluorosulfonic acid membranes, N Zhang, Z Liu, X Ruan, X Yan, Y Song, Z Shen, X Wu, G He, Chemical Engineering Science, 2017, 158, 234-244
[19] Long-spacer-chain imidazolium functionalized poly (ether ether ketone) as hydroxide exchange membrane for fuel cell, X Yan, L Gao, W Zheng, X Ruan, C Zhang, X Wu, G He, International Journal of Hydrogen Energy, 2016, 41 (33), 14982-14990
[18] Molecular dynamics simulation of the hydration structure and hydrogen bonding behavior of phenol in aqueous solution, N Zhang, X Ruan, Y Song, Z Liu, G He, Journal of Molecular Liquids, 2016, 221, 942-948
[17] Effective reclamation of vent gas in ethylbenzene dehydrogenation by coupling multi-stage circle absorption and membrane units, X Ruan, L Wang, Y Dai, N Zhang, X Yan, G He, Separation and Purification Technology, 2016, 168, 265-274
[16] Constructing a rigid crosslinked structure for enhanced conductivity of imidazolium functionalized polysulfone hydroxide exchange membrane, J Dai, G He, X Ruan, W Zheng, Y Pan, X Yan, International Journal of Hydrogen Energy, 2016, 41 (25), 10923-10934
[15] Imidazole functionalized graphene oxide/PEBAX mixed matrix membranes for efficient CO2 capture, Y Dai, X Ruan, Z Yan, K Yang, M Yu, H Li, W Zhao, G He, Separation and Purification Technology, 2016, 166, 171-180
[14] Pressure swing adsorption/membrane hybrid processes for hydrogen purification with a high recovery, B Li, G He, X Jiang, Y Dai, X Ruan, Frontiers of Chemical Science and Engineering, 2016, 10 (2), 255-264
[13] The control and optimization of macro/micro-structure of ion conductive membranes for energy conversion and storage, X Yan, W Zheng, X Ruan, Y Pan, X Wu, G He, Chinese Journal of Chemical Engineering, 2016, 24 (5), 558-571
[12] Membrane assisted cooling crystallization: process model, nucleation, metastable zone, and crystal size distribution, X Jiang, D Lu, W Xiao, X Ruan, J Fang, G He, AIChE Journal 62, 2016, (3), 829-841
[11] Dual-membrane module and its optimal flow pattern for H2/CO2 Separation, B Chen, X Ruan, X Jiang, W Xiao, G He, Industrial & Engineering Chemistry Research, 2016, 55 (4), 1064-1075
[10] Structural characteristics of hydrated protons in the conductive channels: effects of confinement and fluorination studied by molecular dynamics simulation, N Zhang, Y Song, X Ruan, X Yan, Z Liu, Z Shen, X Wu, G He, Physical Chemistry Chemical Physics, 2016, 18 (35), 24198-24209
[9] Bis-ammonium immobilized polystyrenes with co-catalyzing functional end groups as efficient and reusable heterogeneous catalysts for synthesis of cyclic carbonate from CO2 and epoxides, Q Deng, G He, Y Pan, X Ruan, W Zheng, X Yan, RSC Advances, 2016, 6 (3), 2217-2224
[8] High solvent resistance PTFPMS/PEI hollow fiber composite membrane for gas separation, Y Dai, X Ruan, F Bai, M Yu, H Li, Z Zhao, G He, Applied Surface Science, 2016, 360, 164-173
[7] Further separation of HFC-23 and HCFC-22 by coupling multi-stage PDMS membrane unit to cryogenic distillation, X Ruan, Y Dai, L Du, X Yan, G He, B Li, Separation and Purification Technology, 2015, 156, 673-682
[6] A novel membrane distillation response technology for nucleation detection, metastable zone width measurement and analysis, X Jiang, X Ruan, W Xiao, D Lu, G He, Chemical Engineering Science, 2015, 134, 671-680
[5] Synergy of CO2 removal and light hydrocarbon recovery from oil-field associated gas by dual-membrane process, B Chen, X Ruan, W Xiao, X Jiang, G He, Journal of Natural Gas Science and Engineering, 2015, 26, 1254-1263
[4] Particles deposition on microfiltration permeable boundary: modeling and simulation with two-ways coupling sphere model in a turbulent flow, WJ Zhang, XH Ruan, GH He, YL Ma, YF Liu, Engineering Computations, 2015, 32 (4), 1135-1152
[3] Quaternary phosphonium-functionalized poly (ether ether ketone) as highly conductive and alkali-stable hydroxide exchange membrane for fuel cells, X Yan, S Gu, G He, X Wu, W Zheng, X Ruan, Journal of Membrane Science, 2014, 466, 220-228
[2] Chemical potential analysis for directing the optimal design of gas membrane separation frameworks, X Ruan, G He, B Li, X Yan, Y Dai, Chemical Engineering Science, 2014, 107, 245-255
[1] Cleaner recovery of tetrafluoroethylene by coupling residue-recycled polyimide membrane unit to distillation, X Ruan, G He, B Li, J Xiao, Y Dai, Separation and Purification Technology, 2014, 124, 89-98
已授权国外/国际发明专利
[2] Separation and purification coupled process with high helium yield and diversified products, G He, M Guo, Y Dai, X Ruan, P Mi, X Yang, US Patent 11697092, July 2023
[1] Surface modification method based on polymerization and cross-linking solidification of dopamine and/or derivatives thereof, X Ruan, G He, X Liao, Y Xu, X Yan, Y Dai, N Zhang, US Patent 16323452, March 2020
已授权国家发明专利
[60] 一种具有MOFs有序直通通道混合基质膜的制备方法, ZL202210949321.0, 郑文姬, 李子恒, 贺高红, 吴雪梅, 阮雪华, 代岩, 焉晓明
[59] 一种提高ZIFs纳米颗粒在非质子极性溶剂中分散稳定性的方法, ZL202210888522.4, 阮雪华, 刘鑫松, 刘奕舟, 郭雨馨, 贺高红, 王佳铭, 郑文姬, 姜晓滨, 肖武, 宋超
[58] 一种超高负载MOFs基混合基质膜的制备方法, ZL202210639797.4, 郑文姬, 李子恒, 贺高红, 阮雪华, 吴雪梅, 代岩, 焉晓明, 许晨轩, 王利宁, 陈垚, 朴美蕙
[57] 一种原位制碱高效脱除盐湖卤水中镁离子的双极膜系统, ZL202210229588.2, 阮雪华, 姜晓滨, 贺高红, 焉晓明, 陈婉婷, 吴雪梅, 代岩, 李甜甜, 于淼
[56] 一种降低丙烷积累的膜耦合聚丙烯尾气回收工艺, ZL202210167442.X, 贺高红, 周永哲, 阮雪华, 王佳铭, 肖红岩, 肖武, 姜晓滨, 代岩, 郑文姬
[55] 一种综合利用乙烯装置火炬气的膜耦合分离工艺, ZL202210115463.7, 贺高红, 阮雪华, 肖红岩, 王佳铭, 宋春晓, 霍文博, 肖武, 郑文姬, 姜晓滨, 焉晓明
[54] 一种MOFs与聚合物双连续的混合基质膜的制备方法, ZL202210003359.9, 郑文姬, 李子恒, 贺高红, 代岩, 阮雪华, 焉晓明, 李祥村
[53] 一种压缩冷凝、膜分离和吸附耦合的全浓度VOCs捕收系统及方法, ZL202111110056.9, 肖武, 程安迪, 年思宇, 贺高红, 崔启利, 陈先树, 孙晓辉, 陈宏宇, 阮雪华, 姜晓滨
[52] 一种高透气性有机-无机复合纤维气体分离膜的制备方法, ZL202111030820.1, 郑文姬, 刘震, 贺高红, 代岩, 阮雪华, 焉晓明
[51] 一种原位开环反应修饰双功能MOFs混合基质膜的制备方法, ZL202111031126.1, 贺高红, 王东悦, 郑文姬, 阮雪华, 代岩, 焉晓明
[50] 一种焦炉煤气膜分离、蒸汽重整、变压吸附联用制氢方法, ZL202110916307.6, 肖武, 韩晓艺, 程安迪, 阮雪华, 贺高红, 姜晓滨, 李祥村, 吴雪梅
[49] 一种低温强化渗透选择性的含氮天然气膜分离工艺, ZL202110619274.9, 阮雪华, 王佳铭, 贺高红, 宋春晓, 郭明钢, 肖武, 郑文姬, 焉晓明, 姜晓滨
[48] 一种与深冷空分装置耦合集成的压缩空气储能系统, ZL202110065527.2, 阮雪华, 宋春晓, 贺高红, 霍文博, 鲍军江, 肖武, 代岩, 郭明钢
[47] 一种综合利用富氦天然气液化尾气的多目标分离工艺, ZL202110505989.1, 阮雪华, 王佳铭, 贺高红, 李宇鹏, 肖武, 姜晓滨, 代岩, 焉晓明, 郑文姬
[46] 一种基于MXene/ZIF-复合材料的混合基质膜及制备方法, ZL202110386877.9, 李祥村, 牟家微, 代岩, 贺高红, 郑文姬, 焉晓明, 郭明钢, 阮雪华
[45] 亲油/亲水微孔膜协同耦合强化的油水分离工艺, ZL202011630665.2, 阮雪华, 马杨, 贺高红, 王佳铭, 姜晓滨, 代岩, 郑文姬, 焉晓明
[44] 一种促进非质子极性溶剂中ZIF-8合成的方法, ZL201911337493.7, 贺高红, 杨旭茂, 阮雪华, 王佳铭, 郑文姬, 代岩, 焉晓明
[43] 一种用于气体分离的体型缩聚咪唑类聚合物混合基质膜及其制备方法, ZL 202011198997.8, 代岩, 方龙龙, 郑文姬, 贺高红, 阮雪华, 焉晓明, 李祥村
[42] 一种侧基修饰无氧型聚合物阴离子交换膜及其制备方法, ZL201811007760.X, 焉晓明, 苏祥东, 贺高红, 张文君, 阮雪华, 代岩
[41] 一种静电纺丝纳米纤维气体分离膜的制备方法, ZL202011243605.5, 郑文姬, 孙天奇, 贺高红, 焉晓明, 代岩, 阮雪华
[40] 一种多官能化交联型聚亚芳基丁二酮阴离子交换膜及其制备方法, ZL201910576893.7, 焉晓明, 马思瑜, 贺高红, 代岩, 郑文姬, 阮雪华, 高莉, 胡磊, 朱奔
[39] 一种多羟基功能化聚苯并咪唑离子交换膜及制备方法, ZL201910368109.3, 焉晓明, 胡磊, 贺高红, 代岩, 郑文姬, 阮雪华, 吴雪梅
[38] 一种叔胺基两性离子交换膜及其制备方法, ZL201810675369.0, 焉晓明, 张华清, 贺高红, 郑文姬, 代岩, 阮雪华
[37] 一种支化型聚醚醚酮阴离子交换膜及其制备方法, ZL201810576915.5, 焉晓明, 王凯锋, 贺高红, 吴奇, 阮雪华, 代岩, 郑文姬
[36] 一种三甲胺功能化聚芳基吲哚阴离子交换膜及其制备方法, ZL201810774774.8, 焉晓明, 王凯锋, 贺高红, 代岩, 郑文姬, 阮雪华, 潘昱
[35] 一种综合利用醚后碳四的甲基叔丁基醚生产工艺, ZL201910956607.X, 阮雪华, 李海龙, 贺高红, 汤蒙, 陈艺飞, 代岩, 肖武, 郭明钢
[34] 一种疏水侧链修饰烷基磺化聚苯并咪唑两性膜及其制备方法, ZL201810715842.3, 焉晓明, 董子伟, 贺高红, 许坤, 阮雪华, 代岩, 郑文姬
[33] 不含芳基醚键的聚芳哌啶类两性离子交换膜及其制备方法, ZL201810634860.9, 焉晓明, 张华清, 贺高红, 胡钟月, 代岩, 郑文姬, 阮雪华
[32] 一种多胺功能化聚苯并咪唑交联膜及制备方法, ZL201810783483.5, 焉晓明, 胡磊, 贺高红, 阮雪华, 郑文姬, 代岩
[31] 一种煤制氢中氢气提纯与蜡油加氢耦合的系统, ZL201810866485.0, 肖武, 黄伟荣, 姜晓滨, 阮雪华, 贺高红, 李祥村, 吴雪梅
[30] 一种接枝型聚离子液体聚酰亚胺膜及其制备方法, 201810957039.0, 焉晓明, 高毅超, 贺高红, 阮雪华, 代岩, 郑文姬, 潘昱
[29] 一种不含醚氧键型聚合物阴离子交换膜及其制备方法, ZL201811007812.3, 焉晓明, 苏祥东, 贺高红, 张文君, 阮雪华, 代岩
[28] 一种富乙烯裂解干气分级用于乙苯生产装置的分离工艺, ZL201910322137.1, 阮雪华, 贺高红, 肖武, 姜晓滨, 焉晓明, 代岩, 郭明钢, 肖红岩
[27] STAR丙烷脱氢的氢气分离膜内嵌改进的深冷液化系统, ZL201910284132.4, 阮雪华, 贺高红, 肖红岩, 姜晓滨, 肖武, 焉晓明, 代岩, 张宁
[26] 一种非离子型侧链修饰聚苯并咪唑膜及其制备方法, ZL201810714905.3, 焉晓明, 董子伟, 贺高红, 阮雪华, 代岩, 郑文姬
[25] 一种深冷与膜耦合的乙烯循环制冷系统不凝排放气分离回收工艺, ZL201910247722.X, 贺高红, 杨晓航, 阮雪华, 代岩, 郭明钢, 肖红岩
[24] 一种酮与羧酸在电化学氢泵反应器中一步加氢酯化的方法, ZL201810375920.X, 吴雪梅, 贺高红, 宋雪, 黄诗琪, 肖武, 阮雪华, 郑文姬, 范姝艾, 王云晴, 孙嵩岚, 于喆淼
[23] 一种多支链聚芳醚酮阴离子交换膜及其制备方法, ZL201710635250.6, 焉晓明, 刘嘉霏, 贺高红, 阮雪华, 郑文姬, 代岩
[22] 一种哌嗪功能化聚苯醚碱性阴离子交换膜及其制备方法, ZL201710466664.0, 焉晓明, 高莉, 贺高红, 阮雪华, 郑文姬, 代岩, 吴雪梅
[21] 一种多巴胺及其衍生物聚合并交联固化的表面改性方法, ZL201611178888.3, 阮雪华, 廖绪行, 贺高红, 徐燕, 焉晓明, 代岩, 张宁
[20] 一种长支链聚苯醚阴离子膜及其制备方法, ZL201610572946.4, 焉晓明, 高莉, 贺高红, 阮雪华, 郑文姬, 潘昱
[19] 一种梯级利用烟气余热的二氧化碳捕集液化工艺, ZL201610408748.4, 阮雪华, 辛月, 贺高红, 肖武, 代岩, 焉晓明, 张宁
[18] 一种半柔性聚醚砜/酮阴离子交换膜的制备方法, ZL201610032430.0, 焉晓明, 赵宝林, 贺高红, 郑文姬, 阮雪华, 代岩, 潘昱
[17] 负载型双季铵盐催化剂及其制备方法和环状碳酸酯的制备方法, ZL201510916235.X, 焉晓明, 邓庆元, 贺高红, 潘昱, 郑文姬, 阮雪华
[16] 一种负载型季鏻盐催化剂制备环状碳酸酯的方法, ZL201510442688.3, 焉晓明, 邓庆元, 贺高红, 潘昱, 郑文姬, 阮雪华
[15] 膜分离富氧空气强化二段转化炉的布朗合成氨造气工艺, ZL201510250412.5, 阮雪华, 朱婷婷, 贺高红, 焉晓明, 李保军, 郑文姬, 张宁
[14] 一种绿色环保的沼气资源多元化利用工艺, ZL201510252998.9, 阮雪华, 郭明钢, 贺高红, 代岩, 焉晓明, 李保军, 杨招艺
[13] 回收乙烯压缩制冷系统开车尾气的分离工艺, ZL201510250147.0, 阮雪华, 林雪, 贺高红, 代岩, 张宁, 焉晓明, 郑文姬
[12] 一种长支链聚砜阴离子膜及其制备方法, ZL201510213184.4, 焉晓明, 胡玉涛, 贺高红, 阮雪华, 郑文姬, 曾薇, 潘昱
[11] 一种使用膜分离与变压吸附联合处理炼厂气的方法和系统, ZL201410851664.9, 贺高红, 陈博, 阮雪华, 肖武, 姜晓滨, 李保军
[10] 一种提高油田伴生气分离效率并回收二氧化碳的方法, ZL201410526096.5, 贺高红, 陈博, 阮雪华, 肖武
[9] 脱除乙苯脱氢尾气中苯乙烯及回收氢气的方法, ZL201410151133.9, 阮雪华, 贺高红, 李保军, 肖武, 陈博, 代岩
[8] 高通量二氧化碳分离纤维素醚类衍生物复合膜及其制备方法, ZL201310711557.1, 阮雪华, 贺高红, 姚从春, 代岩, 焉晓明, 李保军
[7] 一种减少丁基橡胶生产过程中氯甲烷物耗的方法, ZL201210411264.7, 任纪文, 贺高红, 李保军, 邱正茂, 阮雪华, 陈博, 宋亮
[6] 含氟聚硅氧烷橡胶态复合气体分离膜、制备方法及其应用, ZL201110218649.7, 聂飞, 贺高红, 李保军, 阮雪华, 代岩
[5] 一种含轻烃石油化工气体的处理方法, ZL201110095620.4, 屠伟龙, 阮雪华, 贺高红, 胡江青, 杨云峰, 刘红晶, 高翔宇
[4] 一种提高浅冷回收油田伴生气轻烃效率的方法, ZL201010591309.4, 贺高红, 于长福, 李保军, 阮雪华, 朱向阳, 吴雪梅
[3] 一种高纯度、高回收率提纯焦炉煤气中氢气的方法, ZL201010203034.2, 贺高红, 朱向阳, 王世安, 李保军, 阮雪华, 吴雪梅, 何振, 段振红
[2] 炼厂气集中梯级回收方法, ZL200910011802.1, 贺高红, 李保军, 阮雪华, 苏学锋, 聂飞, 范瑛琦
[1] 合成弛放气中氢气及一氧化碳综合回收的分离方法, ZL200910011406.9, 范瑛琦, 贺高红, 阮雪华, 李保军