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论文类型：期刊论文

发表时间：2013-03-15

发表刊物：CHEMICAL ENGINEERING JOURNAL

收录刊物：SCIE、EI

卷号：220

页面范围：133-142

ISSN号：1385-8947

关键字：Catalytic steam reforming; Glycerol; H-2; Ni-Mg-Al based catalysts

摘要：About 10 wt.% of glycerol can be produced during the conversion of vegetable oils or animal fats into biodiesel fuel by the transesterification process. To make use of glycerol and increase its values, H-2 production from catalytic steam reforming of glycerol by Ni-Mg-Al based catalysts was evaluated experimentally in a fixed-bed reactor under atmospheric pressure within a temperature range of 450-650 degrees C. The thermodynamic analysis was conducted by using a non-stoichiometric methodology based on the minimization of Gibbs free energy. The Ni-Mg-Al based catalysts were synthesized by the co-precipitation method with rising pH technique. The synthesized catalysts were characterized by the elemental analysis, BET, XRD and SEM methods. All the metals in the catalyst remained in oxide forms and the catalysts had the specific surface areas from 98.542 to 126.777 m(2)/g for different compositions. The results showed that glycerol conversion and H-2 selectivity were increased with increasing temperatures from 450 to 650 degrees C. The formations of CH4 and CO in the glycerol steam reforming were almost negligible. Carbon formation in glycerol steam reforming was serious in low temperatures. The catalyst containing NiO of 24.1 wt.%, MgO of 26.1 wt.% and Al2O3 of 49.8 wt.% performed appreciable catalytic activity, and the H-2 selectivity was found to be 78.5% and conversion of glycerol was up to 88.0% at 650 degrees C. The effects of the operating conditions including temperature, the ratio of steam to carbon (S/C), glycerol inlet concentration and flow rate of carrier gas on glycerol steam reforming by the optimized catalyst were tested. Based on a kinetic model assuming the power law with a first reaction order, the activation energy and the frequency factor for glycerol steam reforming by the Ni-Mg-Al based catalysts were calculated. (C) 2013 Elsevier B.V. All rights reserved.