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论文类型： 期刊论文

发表时间： 2018-01-01

发表刊物： RSC ADVANCES

收录刊物： SCIE

卷号： 8

期号： 33

页面范围： 18663-18671

ISSN号： 2046-2069

摘要： A series of Zn-modified Silicalite-1 (S-1) zeolites (Zn-x/S-1) were prepared by the wetness-impregnation method and applied in the catalytic conversion of isobutane. The structure and location of Zn species in Zn-x/S-1 were investigated using UV-Vis and N-2 physical adsorption. The acidity and origin of the acid sites in Zn-x/S-1 were studied by NH3-temperature programmed desorption and Fourier-transform infrared analysis. The catalytic performance of Zn-x/S-1 for isobutane conversion was investigated in a fixed-bed microreactor. In the experiments, the acidity of S-1 zeolite was dramatically increased by modification with Zn, with both Lewis and BrOnsted sites identified in Zn-x/S-1. The relationship between BrOnsted acid sites and Zn-OH groups on ZnO clusters of Zn-x/S-1 was also revealed for the first time. Furthermore, Zn-x/S-1 catalysts exhibited excellent catalytic performances in both isobutane dehydrogenation and butene isomerization reactions. A high selectivity of total butene products ranging from 84.6 to 97.2 was achieved on the catalysts with different Zn loadings. Moreover, the linear correlation between isobutane conversion and the acid amount (determined by NH3-TPD) confirmed that the weak-to-medium acid sites in Zn-x/S-1 should play a key role in isobutane conversion.