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论文类型： 期刊论文

发表时间： 2009-12-10

发表刊物： JOURNAL OF CATALYSIS

收录刊物： SCIE、EI、Scopus

卷号： 268

期号： 2

页面范围： 376-383

ISSN号： 0021-9517

关键字： Liquid-phase reaction; Cascade acylation/dehydration; Micro-/nano-sized H-beta zeolites; Heterogeneous catalysis; 2-Methylanthraquinone; One-pot synthesis

摘要： Liquid-phase cascade acylation/dehydration reactions over various zeolite catalysts were performed to synthesize 2-methylanthraquinone (2-MAQ). Many characterization techniques such as NH3-TPD pyridine-IR BET, XRD, SEM, TEM, XRF, and TGA have been employed to study the relationship between the catalytic behavior and the nature of catalysts. The present work provides evidence that the acidity, pore size, particle size, and surface area of zeolites strongly affect both the catalytic properties and the coke formation. Moreover, it is discovered that the reaction activity of phthalic acid (PA) is higher than that of phthalic anhydride, and the yield of 2-MAQ reached 82.2% when PA was used. which opened a new avenue for one-pot synthesizing 2-MAQ by using PA as an acylation reagent. The catalyst can be recycled four times only with a slight decrease in activity. The nano-sized H-beta zeolite could be a promising liquid-phase cascade acylation/dehydration catalyst for clean one-pot synthesis of 2-MAQ. (c) 2009 Elsevier Inc. All rights reserved.