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论文类型：期刊论文

发表时间：2016-12-01

发表刊物：ACS SUSTAINABLE CHEMISTRY & ENGINEERING

收录刊物：SCIE、EI、Scopus

卷号：4

期号：12

页面范围：6828-6837

ISSN号：2168-0485

关键字：Superhydrophilic; Underwater superoleophobic; Atmospheric pressure plasma; Surface modification; Oil/water separation; Nylon mesh

摘要：Oil/water separation has been addressed by various materials characterized with superwettability, but most of the methods involve corrosive or toxic chemicals which will cause environmental concerns. Proposed herein is an environmentally friendly method to realize oil/water separation. Nylon mesh is exposed to atmospheric pressure plasma for surface modification, by which micro-/nanostructures and oxygen -containing groups are created on nylon fibers. Consequently, the functionalized mesh possesses superhydrophilicity in air and thus superoleophobicity underwater. The water prewetted mesh is then used to separate oil/water mixtures with the separation efficiency above 97.5% for various oil/water mixtures. Results also demonstrate that the functionalized nylon mesh has excellent recyclability and durability in terms of oil/water separation. Additionally, polyurethane sponge slice and polyester fabric are also functionalized and employed to separate oil/water mixtures efficiently, demonstrating the wide suitability of this method. This simple, green, and highly efficient method overcomes a nontrivial hurdle for environmentally safe separation of oil/water mixtures and offers insights into the design of advanced materials for practical oil/water separation.