|
个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Visible light-driven water oxidation catalyzed by mononuclear ruthenium complexes
点击次数：
论文类型：期刊论文
发表时间：2013-01-01
发表刊物：Journal of Catalysis
收录刊物：EI、Scopus
卷号：306
页面范围：129-132
ISSN号：00219517
摘要：A series of mononuclear ruthenium water oxidation catalysts (WOCs) [Ru(bda)L2] (H2bda = 2,2 ?bipyridine-6,6 ? dicarboxylic acid; L = N-cyclic aromatic ligands) were investigated in three-component light-driven water oxidation systems composed of photosensitizers, a sacrificial electron acceptor, and WOCs. A high turnover number of 579 for water oxidation was achieved in the homogeneous system using complex 4 ([Ru(bda)(4-Br-pyridine)2]) as the WOC, and a high quantum efficiency of 17% was found which is a new record for visible light-driven water oxidation in homogeneous systems. © 2013 Elsevier Inc. All rights reserved.