个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
Efficient dye-sensitized solar cells with [copper(6,6 '-dimethyl-2,2 '-bipyridine)(2)](2+/1+) redox shuttle
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论文类型:期刊论文
发表时间:2017-01-01
发表刊物:RSC ADVANCES
收录刊物:SCIE、EI、Scopus
卷号:7
期号:8
页面范围:4611-4615
ISSN号:2046-2069
摘要:The [copper(6,6'-dimethyl-2,2'-bipyridine)(2)](2+/1+) ([Cu(dmbp)(2)](2+/1+))redox couple, which possesses a distorted tetragonal geometry of a Cu(I) complex crystal and a distorted tetrahedral coordination geometry of Cu(II) complex crystal, has been developed as a redox mediator in dye-sensitized solar cells (DSSCs). The energy of loss for dye regeneration was reduced with a very low but sufficient driving force of only 0.11 eV. A distinct increase in open-circuit voltage (V-OC) was achieved and a remarkable power conversion efficiency of 10.3% was afforded at 100 mW cm(-2) under AM 1.5G condition.