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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Characterization of a trinuclear ruthenium species in catalytic water oxidation by Ru(bda)(pic)(2) in neutral media
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论文类型：期刊论文
发表时间：2016-06-30
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：SCIE、PubMed
卷号：52
期号：55
页面范围：8619-8622
ISSN号：1359-7345
摘要：A Ru-III-O-Ru-IV-O-Ru-III type trinuclear species was crystallographically characterized in water oxidation by Ru(bda)(pic)(2) (H(2)bda = 2,2'-bipyridine- 6,60-dicarboxylic acid; pic = 4-picoline) under neutral conditions. The formation of a ruthenium trimer due to the reaction of Ru-IV QO with Ru-II-OH2 was fully confirmed by chemical, electrochemical and photochemical methods. Since the oxidation of the trimer was proposed to lead to catalyst decomposition, the photocatalytic water oxidation activity was rationally improved by the suppression of the formation of the trimer.