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论文类型：期刊论文

发表时间：2019-05-01

发表刊物：Nano Energy

收录刊物：EI

卷号：59

页面范围：537-544

ISSN号：22112855

关键字：Charge transfer; Electric fields; Energy conversion; Heterojunctions; Indium compounds; Nanosheets; Nickel sulfates; Semiconductor quantum dots; Solar energy; Tungsten compounds; Van der Waals forces, First principle calculations; Hydrogen evolution rate; Interfacial design; Internal electric fields; Photocatalytic water splitting; Photoexcited carriers; Spontaneous formation; Two Dimensional (2 D), Zinc compounds

摘要：Developing robust water splitting photocatalyst remains a pivot challenge for solar-to-fuel conversion. Herein, two-dimensional (2D) Janus bilayer heterostructures are reported by sulfur-vacancy-confined-in ZnIn2S4 (Vs-ZnIn2S4) and WO3 nanosheets as an all-solid-state Z-scheme prototype. First-principle calculations and experimental observations clearly confirm the spontaneous formation of this redox-mediator-free Z-scheme van der Waals heterostructure at atomic level, not only facilitating the space separation of photoexcited carriers with high charge density, enhancing charge dynamics and optimizing charge lifetime, but also accumulating electrons in conduction band of Vs-ZnIn2S4 and holes in valence band of WO3 by internal electric field through W CS bonds. After integrated by NiS quantum dots, novel 2D/2D NiS/Vs-ZnIn2S4/WO3 heterostructures with high stability exhibited an outstanding visible-light hydrogen evolution rate of 11.09 mmol g?1 h?1 and an apparent quantum efficiency about 72% at 420 nm, the highest value so far reported among the family of ZnIn2S4 photocatalysts. This work not only presents novel Janus heterostructures but also paves the atomic-level structural and interfacial design and the construction of 2D Janus bilayer Z-scheme heterojunctions for solar energy conversion applications. ? 2019