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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Homogeneous Oxidation of Water by Iron Complexes with Macrocyclic Ligands
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论文类型：期刊论文
发表时间：2014-06-01
发表刊物：CHEMISTRY-AN ASIAN JOURNAL
收录刊物：SCIE、EI、PubMed、Scopus
卷号：9
期号：6
页面范围：1515-1518
ISSN号：1861-4728
关键字：homogeneous catalysis; iron complex; oxygen evolution; renewable resources; water splitting
摘要：The activity of eleven separated iron complexes and nine in situ-generated iron complexes towards catalytic water oxidation have been examined in aqueous solutions with Ce(NH4)(2)(NO3)(6) as the oxidant. Two iron complexes bearing tridentate and tetradentate macrocyclic ligands were found to be novel water oxidation catalysts. The one with tetradentate ligand exhibited a promising activity with a turnover number of 65 for oxygen evolution.