孙立成

个人信息Personal Information

教授

博士生导师

硕士生导师

主要任职:无

其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工

办公地点:大连理工大学西部校区化工实验楼E-223

联系方式:0411-84986493

电子邮箱:sunlc@dlut.edu.cn

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Molecular engineering of small molecules donor materials based on phenoxazine core unit for solution-processed organic solar cells

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论文类型:期刊论文

发表时间:2014-07-21

发表刊物:JOURNAL OF MATERIALS CHEMISTRY A

收录刊物:SCIE、EI、Scopus

卷号:2

期号:27

页面范围:10465-10469

ISSN号:2050-7488

摘要:A D-pi-A type small molecule POZ4 and a A-pi-D-pi-A type small molecule POZ6, in which phenoxazine was used as the central building block and dicyanovinyl was employed as the electron-withdrawing end-group, have been designed and synthesized. Compared with D-pi-A type donor material POZ4, the donor material POZ6 with A-pi-D-pi-A configuration shows much wider response to solar light. An efficiency of 5.60% was obtained for the POZ6: PC71BM based solar cells, and the device fabricated with POZ6:PC71BM (1 : 1) showed a much better balanced hole and electron mobility of 2.24 x 10(-4) cm(2) V-1 s(-1) and 3.17 x 10(-4) cm(2) V-1 s(-1), respectively.