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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
Promoting the Activity of Catalysts for the Oxidation of Water with Bridged Dinuclear Ruthenium Complexes
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论文类型:期刊论文
发表时间:2013-03-18
发表刊物:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物:SCIE、EI、PubMed、Scopus
卷号:52
期号:12
页面范围:3398-3401
ISSN号:1433-7851
关键字:artificial photosynthesis; binuclear catalyst; homogeneous catalysis; solar fuels; water splitting
摘要:Solar fuels: Dinuclear ruthenium catalysts prepared from two covalently bridged monomeric catalytic units show outstanding activities towards the oxidation of water with high turnover numbers up to 43 000 and turnover frequencies up to 40 s-1 (see picture). Direct comparison of the performance parameters indicates that the dimers are significantly more active as catalysts than the monomers. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.