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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Approaches to efficient molecular catalyst systems for photochemical H-2 production using [FeFe]-hydrogenase active site mimics
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论文类型：期刊论文
发表时间：2011-12-28
发表刊物：DALTON TRANSACTIONS
收录刊物：PubMed、SCIE、Scopus
卷号：40
期号：48
页面范围：12793-12800
ISSN号：1477-9226
摘要：The research on structural and functional biomimics of the active site of [FeFe]-hydrogenases is in an attempt to elucidate the mechanisms of H-2-evolution and uptake at the [FeFe]-hydrogenase active site, and to learn from Nature how to create highly efficient H-2-production catalyst systems. Undoubtedly, it is a challenging, arduous, and long-term work. In this perspective, the progresses in approaches to photochemical H-2 production using mimics of the [FeFe]-hydrogenase active site as catalysts in the last three years are reviewed, with emphasis on adjustment of the redox potentials and hydrophilicity of the [FeFe]-hydrogenase active site mimics to make them efficient catalysts for H-2 production. With gradually increasing understanding of the chemistry of the [FeFe]-hydrogenases and their mimics, more bio-inspired proton reduction catalysts with significantly improved efficiency of H-2 production will be realized in the future.