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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Asymmetric oxidation of sulfides with hydrogen peroxide catalyzed by a vanadium complex of a new chiral NOO-ligand
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论文类型：期刊论文
发表时间：2009-12-15
发表刊物：CATALYSIS COMMUNICATIONS
收录刊物：SCIE
卷号：11
期号：4
页面范围：294-297
ISSN号：1566-7367
关键字：Asymmetric oxidation; Chiral NOO-ligand; Chiral sulfoxide; Sulfoxidation; Vanadium catalyst
摘要：A new chiral NOO-tridentate ligand (8R)-2-(2-hydroxyphenyl)-4-methyl-5,6,7.8-tetrahydro-quinolin-8-ol (1) bearing a rigid tetrahydroquinoline framework was prepared and applied in the vanadium-catalyzed asymmetric oxidation of aryl methyl sulfides with H(2)O(2) as oxidant. Less toxic acetone was found to be the proper solvent for the enantioselective oxidation of sulfides. Under the optimal condition, the asymmetric oxidation of aryl methyl sulfides in acetone catalyzed by VO(acac)(2)/1 at 0 degrees C gives good to high yields (80-95%) of sulfoxides with enantioselectivity up to 77% ee. (C) 2009 Elsevier B.V. All rights reserved.