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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Photochemical hydrogen production catalyzed by polypyridyl ruthenium-cobaloxime heterobinuclear complexes with different bridges
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论文类型：期刊论文
发表时间：2009-08-01
发表刊物：JOURNAL OF ORGANOMETALLIC CHEMISTRY
收录刊物：SCIE
卷号：694
期号：17
页面范围：2814-2819
ISSN号：0022-328X
关键字：Cobaloxime; Heterobinuclear complex; Hydrogen production; Photocatalysis; Ruthenium photosensitizer
摘要：Two heterobinuclear complexes [(bpy)(2)Ru(bpy-4-CH(3),4'-CONH(4-py)Co(dmgBF(2))(2)(OH(2))](PF(6))(2) (1, dmgBF(2) = (difluoroboryl) dimethylglyoximato) and [(bpy)(2)Ru(bpy-4-CH(3),4'-CONHCH(2)(4-py)Co(dmgBF(2))(2)(OH(2))](PF(6))(2) (2) were prepared, in which the polypyridyl ruthenium photosensitizer and the cobaloxime catalyst are connected either by a conjugated bridge (1) or by an unconjugated one (2). Complexes 1 and 2 were used as photocatalysts for hydrogen generation. Under optimal conditions, the turnover numbers (ton) for hydrogen evolution were 38 for 1 and 48 for 2 in the presence of 300 equiv of both Et(3)N and [Et(3)NH][BF(4)] in the acetone solution during an 8-h irradiation of visible light (lambda > ca. 400 nm). The complex 2 with an unconjugated bridge proved to be more efficient for photochemical hydrogen generation than the complex 1 with a conjugated bridge under the same reaction condition. (C) 2009 Elsevier B.V. All rights reserved.