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论文类型：期刊论文

发表时间：2009-01-01

发表刊物：JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

收录刊物：SCIE、EI

卷号：22

期号：1

页面范围：1-8

ISSN号：0894-3230

关键字：Electrogenerated Chemiluminescence (ECL); 15-Crown-5 derivatives; Annihilation ECL; Co-reactant ECL

摘要：Novel electrogenerated chemiluminescence (ECL) reagents C1, C2, and C3 with high fluorescence quantum yields bearing 15-crown-5 moiety have been synthesized and characterized. The photophysical, electrochemical, and ECL characters of these compounds have been studied in a 1:1 (v/v) PhH/MeCN mixed solvent. The ECL intensity is enhanced distinctly with the increase in the fluorescence quantum yield. Their ECL behaviors have been studied using annihilation and co-reactant methods (tri-n-propylamine (TPrA) was used as a co-reactant), respectively. The stable ECL emissions of compounds C1-C3 can be ascribed to the typical and simple monomer ECL emission via S-route. Copyright (c) 2008 John Wiley & Sons, Ltd.