|
个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Redox-induced partner radical formation and its dynamic balance with radical dimer in cucurbit[8]uril
点击次数：
论文类型：期刊论文
发表时间：2009-12-21
发表刊物：PHYSICAL CHEMISTRY CHEMICAL PHYSICS
收录刊物：SCIE、PubMed、Scopus
卷号：11
期号：47
页面范围：11134-11139
ISSN号：1463-9076
摘要：N-(4-Hydroxy-phenoxyethyl)-N'-ethyl-4,4'-bipyridium (1) can form a stable 1 : 1 inclusion complex with CB[8] in aqueous solution, in which the hydroxyphenol (HP) moiety is back-folded and inserted together with the viologen moiety into the cavity of CB[8]. When the ethyl viologen dication (EV2+) in 1 is reduced, chemically or electrochemically, an intramolecular partner radical (EV+center dot-HP)/CB[8] can be detected, meanwhile, a dynamic balance between the partner radical and the intermolecular radical dimer (EV+center dot-HP)(2)/CB[8] can be observed.
上一条：Highly efficient molecular catalysts for visible light driven water oxidation-towards solar energy conversion into fules（邀请报告）
下一条：Preparation, Facile Deprotonation, and Rapid H/D Exchange of the mu-Hydride Diiron Model Complexes of the [FeFe]-Hydrogenase Containing a Pendant Amine in a Chelating Diphosphine Ligand