个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
Octacarbonyl(5-methoxy-2,3-dihydro1H-benzimidazol-2-yl)di-mu 3-sulfido-diiron(I) iron(II)(2 Fe-Fe)
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论文类型:期刊论文
发表时间:2008-01-01
发表刊物:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
收录刊物:SCIE、PubMed
卷号:64
期号:Pt 1
页面范围:M217-U2091
ISSN号:1600-5368
摘要:The title compound, [Fe-3(C8H8N2O)S-2(CO)(8)], was prepared by the direct reaction of Fe-3(CO)(12) and 5-methoxy-1H-benzoimidazole-2- thiol in tetrahydrofuran. Desulfurization took place readily to form a sulfide carbonyl cluster. The molecule contains a triangle consisting of three Fe atoms capped by two S atoms above and below. There are two Fe Fe bonds [2.6322 (5) and 2.5582 (5) angstrom] in the triangle; the length of the third edge [3.3987 (5) angstrom] is too long to represent an Fe-Fe bond.