大连理工大学主页平台管理系统孙立成--中文主页-- Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes

论文成果

Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes

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论文类型：期刊论文
发表时间：2007-09-01
发表刊物：EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
收录刊物：SCIE、Scopus
文献类型：J
期号：26
页面范围：4128-4131
ISSN号：1434-1948
关键字：benzimidazolyl ligand; redox switch; reversible protonation and deprotonation; Ru-II complex
摘要：A monoruthenium(II) complex of the benzimidazolyl ligand and its deprotonated counterpart were prepared and structurally characterized. The reversible protonation/deprotonation process of the ancillary ligand switches the redox potential of the ruthenium(II) core from 0.69 to 0.26 V vs. Ag/AgNO3. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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