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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Pentacarbonyl-1 kappa C-2,2 kappa 3C-(diphenyl-phosphine-1kP)(mu-2-propyl-2-aza-propane-1,3-dithiolato-1 kappa S-2,S ': 2 kappa S-2,S ')diiron(Fe-Fe)
点击次数：
论文类型：期刊论文
发表时间：2007-07-01
发表刊物：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
收录刊物：SCIE
卷号：63
页面范围：M1959-U1552
ISSN号：1600-5368
摘要：The title compound, [Fe-2(C5H11NS2)(C12H11P)(CO)(5)], has been prepared and characterized as a model compound of the iron hydrogenase active site through controlled CO ligand displacement of (mu-SCH2)(2)N(CH2CH2CH3)[Fe-2(CO)(6)] with diphenylphosphine. The central Fe2S2 structure is in a butterfly conformation, and each Fe atom displays pseudo-square-pyramidal geometry. The phosphine group occupies an apical position. The propyl group on the bridging N atom is in an equatorial position and takes a zigzag form. In the crystal packing, adjacent pairs of molecules are associated by S center dot center dot center dot S (3.625 angstrom) intermolecular nonbonded weak interactions.