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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Fe-S complexes containing five-membered heterocycles: novel models for the active site of hydrogenases with unusual low reduction potential
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论文类型：期刊论文
发表时间：2007-02-28
发表刊物：DALTON TRANSACTIONS
收录刊物：SCIE、EI、PubMed
期号：8
页面范围：896-902
ISSN号：1477-9226
摘要：Three biomimetic 2Fe2S complexes [{(mu-SCH2)(2)NCH2(2-C4H3O)}](Fe-2(CO)(6)) (6a), [{(mu-SCH2)(2) NCH2(2-C4H3S)}](Fe-2(CO)(6)) (6b) and [{(mu-SCH2)(2)NCH2(5-Br-2-C4H2S)}Fe-2(CO)(6)] (6c) were prepared as models for the active site of Fe-only hydrogenase by the convergent process from [(mu-S-2)Fe-2(CO)(6)] and N,N-bis(hydromethyl)-2-furan and thiophene. The structures of these complexes were identified spectroscopically and crystallographically. The electrochemical behavior of the complexes 6a and 6c was unique as they showed catalytic proton reduction with a low reduction potential at -1.13 and -1.09 V vs Fc/Fc(+), respectively, in the presence of HClO4.