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论文类型：期刊论文

发表时间：2006-11-23

发表刊物：APPLIED CATALYSIS A-GENERAL

收录刊物：SCIE、EI、Scopus

卷号：315

页面范围：120-127

ISSN号：0926-860X

关键字：asymmetric epoxidation; chromene; dimeric manganese complex; salen ligand; styrene

摘要：Two dimeric chiral (pyrrolidine salen)Mn(III) complexes 3 and 4 were prepared, in which the two (pyrrolidine salen)Mn(III) units are linked either by a p-xylylene or by ap-phthalyl bridge. High yields were attained for asymmetric epoxidation of styrene and substituted chromenes at 0.5-4.0 mol% catalyst loading of 3 and 4 using NaClO/PPNO and m-CPBA/NMO as oxidant systems, with 37-39% ee for styrene and 86-95% ee for substituted chromenes. Dimeric complexes 3 and 4 displayed higher activities than their parent monomeric complexes 1 and 2 of double equiv for epoxidation of substituted chromenes. Complex 3 bearing two tertiary amine units displayed considerably higher activity than analogous dimeric complex 4 containing two carboxamide units in the aforementioned reaction. The effect of excess CH3I on the epoxidation of 6-nitro-2,2-dimethylchromene catalysed by 3 in the aqueous/organic biphasic medium was explored. The recovery and recycling possibilities of the dimeric complexes 3 and 4 were studied. (c) 2006 Elsevier B.V. All rights reserved.