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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Aryl-diamide bridged binuclear ruthenium(II) tris(bipyridine) complexes: Synthesis, photophysical, electrochemical and electrochemiluminescence properties
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论文类型：期刊论文
发表时间：2006-10-01
发表刊物：JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷号：691
期号：20
页面范围：4189-4195
ISSN号：0022-328X
关键字：binuclear ruthenium complexes; electrochemiluminescence; polypyridine ligands; synthesis
摘要：Several new symmetrical aromatic hydrocarbon bridged bipyridine ligands and their binuclear Ru (II) complexes have been designed, synthesized and characterized on the basis of (1)H NMR, MS and HRMS. Their absorption and emission properties, electrochemical behaviors and electrochemical luminescence were investigated. All ruthenium complexes show characteristic MLCT absorption and similar redox potential. Among the three complexes reported, 4c has the best electrochemical luminescence property. (c) 2006 Elsevier B.V. All rights reserved.