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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Synthesis, structures and electrochemical properties of amino-derivatives of diiron azadithiolates as active site models of Fe-only hydrogenase
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论文类型：期刊论文
发表时间：2006-03-01
发表刊物：INORGANICA CHIMICA ACTA
收录刊物：SCIE
卷号：359
期号：4
页面范围：1071-1080
ISSN号：0020-1693
关键字：bioinorganic chemistry; catalysis; hydrogen production; iron-sulfur complex
摘要：The preparation and characterization of two novel amino-incorporated sulfur-bridged dinuclear iron (I) complexes of the type [NR(mu-SCH(2))2]Fe(2)(CO)(6), one being amino protected [N(CH(2)CH(2)NHTs)(mu-SCH(2))(2)]Fe(2)(CO)(6) (8) and the other [(mu-SCH(2))(2)Fe(2)(-CO)(6)NCH(2)CH(2)N (mu-SCH(2))(2)]Fe(2)(CO)(6) (9) are described. These two complexes are readily prepared in a S(N)2 manner between double lithium anion and bis(chloromethyl) amine derivatives. The structures of 8 and 9 were characterized by IR, (1)H, (13)C NMR, MS and HRMS spectra and further determined by X-ray analyses. Protonation of complex 8 gave the mono N-protonated product, while for 9 the protonation occurred in both of the N atoms. The redox properties were evaluated by cyclic voltammograms. It was shown that these two complexes can catalyze electrochemical reduction of proton to molecular hydrogen. (c) 2005 Elsevier B.V. All rights reserved.