个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
Synthesis of two novel rhenium(I) bipyridyl photosensitive dyes
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论文类型:期刊论文
发表时间:2004-08-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:Scopus、SCIE、ISTIC
卷号:15
期号:8
页面范围:965-968
ISSN号:1001-8417
关键字:Rhenium(I) 2, 2 '-bipyridyl complex; photosensitizer; red shift
摘要:Two novel rhenium(I) 2, 2'-bipyridyl complexes, [(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and [(4,4'-di-COOEt-bipy) Re (CO)(3) (NCS)], a model complex [(4,4'-di-COOEt-bipy) Re (CO)(3) (pyridine)PF6], were synthesized. Their ground state electronic spectra and emission spectra were measured in acetonitrile. The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.