个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
Structural transformation mediated by o-, m-, and p-phthalates from two to three dimensions for manganese/phthalate/4,4 '-bpy complexes (4,4 '-bpy=4,4 '-bipyridine)
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论文类型:期刊论文
发表时间:2003-01-01
发表刊物:NEW JOURNAL OF CHEMISTRY
收录刊物:Scopus、SCIE
卷号:27
期号:5
页面范围:890-894
ISSN号:1144-0546
摘要:Three isomers of o-, m-, and p-phthalate are used to link together Mn centres, resulting in [Mn(phth)(H2O)(x)](n) moieties ( phth = phthalate dianion) with single-chain, double-chain and sheet structures, respectively, which predetermine the extended structures derived from the crosslinkage of 4,4'-bipyridine, and show the influence of isomerism of the phthalate on topological changes of the final polymers from two dimensional (2D) single-layer, double-layer to 3D network architectures. These structural changes in topology are correlated with the differences in the magnetic and optical properties of the polymers.