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论文类型：期刊论文

发表时间：2014-01-05

发表刊物：CATALYSIS COMMUNICATIONS

收录刊物：SCIE、EI

卷号：43

页面范围：21-24

ISSN号：1566-7367

关键字：Ni2P; Passivation; H2S; O-2; XAS; Hydrodesulfurization

摘要：Ni2P/MCM-41 with a stoichiometric Ni/P ratio prepared using a H-2 plasma reduction method was passivated either by 10.0 vol.% H2S/H-2 (Ni2P-S) or 1.0 vol.% O-2/He (Ni2P-O). The XAS characterization demonstrated that the Ni-P bond of Ni2P was more sensitive to O-2 than the Ni-Ni bond while H2S mainly reacted with Ni-Ni site. Moreover, Ni species in Ni2P-S was more electron-deficient. The different hydrodesulfurization performances of Ni2P-S and Ni2P-O were discussed by considering their different structure and electronic properties as well as the formation of a covalent nickel phosphosulfide phase. (C) 2013 Elsevier B.V. All rights reserved.