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发布时间：2019-11-08

论文类型：期刊论文

发表时间：2019-06-05

发表刊物：APPLIED CATALYSIS B-ENVIRONMENTAL

收录刊物：EI、SCIE

卷号：246

页面范围：330-336

ISSN号：0926-3373

关键字：Metal phosphides; Sulfur doped g-C3N4; Noble metal-free; Photocatalysis; Hydrogen generation

摘要：Iron group transition metal phosphides (TMPs, M = Fe, Co, Ni) have been considered as promising noble-metal-free cocatalysts for the photocatalytic hydrogen (H-2) generation. However, the impact on the H-2 generation activity in correlation with the types of metal in TMPs still remains unresolved. In this paper, to investigate the effect of metal phosphides with different metal on photocatalytic H-2 generation, three types of iron group transition metal phosphides (M2P, M = Fe, Co, and Ni) nanoparticles were used as the cocatalysts of sulfur doped g-C3N4 (S-CN) for the photocatalytic H-2 generation. By comparing three types of M2P/S-CN, the optimum cocatalyst of Ni2P has ca. 22.7 times that of the pristine S-CN under the same condition. The photoluminescence (PL) spectra, photoelectrochemical characterization and DFT calculations confirmed the enhanced photo-induced charge transfer and band separation when S-CN was integrated with the Ni2P.