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论文类型：期刊论文

发表时间：2014-09-15

发表刊物：CONSTRUCTION AND BUILDING MATERIALS

收录刊物：SCIE、EI、Scopus

卷号：66

页面范围：154-162

ISSN号：0950-0618

关键字：Pisha Sandstone; NaOH-activated; Steel slag; Hydration process; Carbonation process; Compressive strength

摘要：Pisha Sandstone which caused severe soil erosion is a kind of arenite formed during the Tertiary period in northwest China. Pisha Sandstone when combined with suitable alkali activators and mineral additives can be converted into alkali-activated cement. The compressive strength of alkali-activated Pisha Sandstone at different slag replacement levels, different NaOH dosages and ages were examined. Scanning electron microscopy (SEM)/energy dispersive X-ray (EDS), Fourier transformed infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were used to analyze the hydration process and carbonation process of alkali-activated Pisha Sandstone. TG/DTG was used to quantify the amounts of carbonates which formed from calcium silicate hydrate (C-S-H) at different steel slag additions and ages. The compressive strength of Pisha Sandstone with suitable activators (1% NaOH) and mineral additives (40% steel slag) can reach 46 MPa at 90 days. The results of SEM/EDS, FTIR, XRD and TG/DTG showed the products of NaOH-activated Pisha Sandstone are C-S-H gel and geopolymer gel. However it also showed serious carbonation of C-S-H gel. In particular, the results of TGA/DTG showed that the carbonation rate of tobermorite in C3 reached 37.8% at 28 days. But the carbonation rates of C-S-H gel decreased with the increasing of slag dosages and NaOH concentrations. (C) 2014 Elsevier Ltd. All rights reserved.