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论文类型：期刊论文

发表时间：2018-11-01

发表刊物：WATER RESEARCH

收录刊物：PubMed、SCIE、Scopus

卷号：144

页面范围：365-372

ISSN号：0043-1354

关键字：Mariculture; Reverse osmosis; Electrodialysis; Dissolved organic matter; Sulfonamide antibiotics; Photodegradation

摘要：Mariculture activities and river inputs lead to coastal seawaters with DOM levels that are comparable to or even higher than those in terrestrial water bodies. However, effects of seawater DOM, and especially of DOM occurring in areas impacted by mariculture, on photodegradation of organic micropollutants, are largely unknown. In this study, simulated sunlight irradiation experiments were performed to probe the effects of DOM extracted from mariculture impacted seawaters and from offshore areas, on photo degradation of three sulfonamide antibiotics (SAs). Results show that the SAs are transformed mainly by indirect photodegradation induced by triplet excited DOM ((DOM)-D-3*). Compared with DOM from the more pristine coastal waters, the DOM from mariculture impacted areas undergoes less photobleaching, contains higher percentage of humic-like materials and higher proportions of aromatic and carbonyl structures. Thus, the DOM from mariculture areas exhibits higher rates of light absorption, higher formation quantum yields of (DOM)-D-3*, higher (DOM)-D-3* steady-state concentrations and higher reactivity on photodegradation of the SAs. Photochemistry of the seawater DOM is different from that reported for freshwater lake DOM. This study highlights the importance of probing the effects of DOM from coastal seawaters on photodegradation of organic micropollutants since coastal seawaters are sinks of many aquatic pollutants. (C) 2018 Elsevier Ltd. All rights reserved.