点击次数：

论文类型：期刊论文

发表时间：2014-10-01

发表刊物：JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION

收录刊物：SCIE、EI、ISTIC

卷号：29

期号：5

页面范围：877-884

ISSN号：1000-2413

关键字：silica aerogels; PMMA; diatomite; ambient pressure drying; mechanical properties

摘要：Diatomite was used as raw material to prepare sodium silicate with a modulus of 3.1 by alkali dissolution method and the resulted sodium silicate solution was employed as a precursor. Methyl methacrylate monomers were introduced in wet gels through solution-immersion, and upon heating at 70 degrees, the mesoporous surfaces throughout the skeletal framework were coated with the polymer layer. PMMA modified silica aerogels were successfully synthesized via ambient pressure drying. The properties were investigated by FTIR, NMR, TGA, nitrogen adsorption-desorption, FESEM and nano-indentation, etc. Results indicate that with the increasing of PMMA incorporated into silica aerogels, the bulk density and the BET surface area increase, the porosity decreases. Through the observation of FESEM, it is found that the interconnecting pores and the big pores add, the pore size distribution expands from 5-17 to 28-150 nm. By comparison, the PMMA modified silica aerogels achieve a 52-fold increase in hardness and a 10-fold increase in modulus.