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论文类型：期刊论文

发表时间：2013-07-01

发表刊物：MAGNETIC RESONANCE IN CHEMISTRY

收录刊物：SCIE、PubMed、Scopus

卷号：51

期号：7

页面范围：431-434

ISSN号：0749-1581

关键字：NMR; 1 H NMR; 13C NMR; 2D NMR; synthesis

摘要：A one-step method was reported for the synthesis of 6-acetamido-3-(N-(2-(dimethylamino) ethyl) sulfamoyl) naphthalene-1-yl 7-acetamido-4-hydroxynaphthalene-2-sulfonate by treating 7-acetamido-4-hydroxy-2-naphthalenesulfonyl chloride with equal moles of N, N-dimethylethylenediamine in acetonitrile in the presence of K2CO3. The chemical structure of the obtained compounds was characterized by MS, FTIR, 1H NMR, 13C NMR, gCOSY, TOCSY, gHSQC, and gHMBC. The chemical shift differences of 1H and 13C being 0.04 and 0.2, respectively, were unambiguously differentiated. Copyright (c) 2013 John Wiley & Sons, Ltd.