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论文类型：期刊论文

发表时间：2018-03-15

发表刊物：MICROPOROUS AND MESOPOROUS MATERIALS

收录刊物：SCIE

卷号：259

页面范围：229-237

ISSN号：1387-1811

关键字：Ionic liquid; sp(2) hybridization; Heteroatom doping; Carbon network; Supercapacitors

摘要：The utilization of ionic liquids as electrolyte is beneficial for realization of high energy density super capacitors due to their high operation voltage. Nevertheless, ionic liquids electrolytes suffer from sluggish ion diffusion and poor wetting behavior on porous electrodes as a result of large ion sizes and high viscosity, which has severely hindered their practical use. Herein, highly sp(2) hybridized and nitrogen, oxygen dual-doped nanoporous carbon networks were prepared based on charge-induced self-assembly strategy using chitosan as carbon precursor with reduced graphene oxide (GO) in between as conductive scaffolds. The optimized material as supercapacitor electrodes exhibits an outstanding specific capacitance of 201 F g(-1) in 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4) electrolyte at 0.5 A g(-1) with a maximum energy density of 111 Wh kg(-1), superior to numerous reported values, which are attributed to multiple synergistic effects of several beneficial characteristics, that is, excellent conductivity deduced from highly sp(2) hybridized carbon originated from carbonized chitosan and graphene conductive scaffolds being in favor of rate performance and cyclic stability, nitrogen and oxygen functionalization improving the surface wettability with electrolyte as well as contributing to the capacitance, large specific surface areas providing abundant active sites to boost charge capacity, and sheet-like structures effectively shortening diffusion pathways to improve ion transports. (C) 2017 Published by Elsevier Inc.