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个人信息Personal Information
教授
博士生导师
硕士生导师
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:化学工艺. 能源化工. 工业催化
办公地点:大连市凌工路2号大连理工大学西部校区化工实验楼C331室
联系方式:0411-84986355
电子邮箱:wencuili@dlut.edu.cn
Insight into Structure-Dependent Self-Activation Mechanism in a Confined Nanospace of Core-Shell Nanocomposites
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论文类型:期刊论文
发表时间:2013-06-24
发表刊物:SMALL
收录刊物:SCIE、EI、PubMed、Scopus
卷号:9
期号:12
页面范围:2086-2090
ISSN号:1613-6810
关键字:nanocomposites; pyrolysis; hollow carbon nanospheres; core-shells; silica
摘要:An unusual hollow core expansion through in situ self-activation in a confined nanospace is observed, which is due to the different physical and chemical properties of the core and shell. The in situ generated gas molecules (e.g., CO2, H2O) preferentially assemble in the hollow core and create immense pressure, which can gasify the formed carbon shells, resulting in substantially increased porosity and a hollow cavity. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.