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论文类型：期刊论文

发表时间：2012-05-01

发表刊物：MICROPOROUS AND MESOPOROUS MATERIALS

收录刊物：SCIE、EI

卷号：153

页面范围：247-253

ISSN号：1387-1811

关键字：Mesoporous materials; Hybrid supercapacitor; Manganese dioxide; Birnessite; Acid treatment

摘要：High surface area mesoporous manganese dioxide (MnO2) with ca-phase crystalline structure has been synthesized by the reduction of potassium permanganate with ethylene glycol under acidic conditions. Nitrogen sorption analyses show that MnO2 synthesized under acidic conditions exhibits a type IV isotherm, indicating a mesoporous character. Electrochemical performances of MnO2 samples as supercapacitor electrode materials have been studied in a three-electrode system. A hybrid supercapacitor based on using a composite material (MnO2&Activated Carbon) as the positive electrode and activated carbon as the negative electrode has been fabricated. The hybrid supercapacitor fabricated using MnO2 synthesized under acidic conditions has excellent large current charge-discharge performance, and shows a practical cell voltage of 1.8 V and a capacitance of 22.1 F g(-1) after 1500 cycles even in the presence of the dissolved oxygen. MnO2 synthesized in the absence of acid shows poor cycle performance and a low capacitance. (C) 2012 Elsevier Inc. All rights reserved.