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论文类型： 期刊论文

发表时间： 2014-01-22

发表刊物： SEPARATION SCIENCE AND TECHNOLOGY

收录刊物： SCIE、EI

卷号： 49

期号： 2

页面范围： 305-310

ISSN号： 0149-6395

关键字： alloy refining; segregation coefficient; Si-Al-Sn alloy; solar-grade silicon

摘要： Numerous studies have searched for methods of Si refining for the production of photovoltaic cells to alleviate the global shortage of solar-grade Si. An alloy refining progress with a Si-Al-Sn melt was developed in this paper. To elucidate the relationship between Sn and B, the interaction parameter between them at 1173K was determined as 2506 +/- 143. This result indicated the strongly repulsive force between Sn and B. Thermodynamic analysis and experiments showed that the purification efficiency of Si-Al-Sn alloy weakened with increased Sn content in the melt.