Small molecule activation and biomimetic catalysis
Paper
Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.
Release Time:2019-03-11
Hits:
Indexed by:
Journal Article
First Author:
Sun Xing-Yu
Correspondence Author:
Ren, WM; Lu, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
Co-author:
Lu Xiao-Bing,Liu Si-Jie,Jia Yin-Bao,Wang Yi-Ming,Ren Wei-Min
Date of Publication:
2018-02-21
Journal:
Molecules (Basel, Switzerland)
Included Journals:
PubMed、SCIE
Document Type:
J
Volume:
23
Issue:
2
ISSN:
1420-3049
Key Words:
Lewis pair polymerization,block copolymers,brush copolymers,click reaction,organocatalytic ring-opening polymerization
Abstract:
Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.