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Tandem Lewis Pair Polymerization and Organocatalytic Ring-Opening Polymerization for Synthesizing Block and Brush Copolymers.

发表时间:2019-03-11
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论文类型:
期刊论文
第一作者:
Sun Xing-Yu
通讯作者:
Ren, WM; Lu, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, 2 Linggong Rd, Dalian 116024, Peoples R China.
合写作者:
Ren Wei-Min,Liu Si-Jie,Jia Yin-Bao,Wang Yi-Ming,Lu Xiao-Bing
发表时间:
2018-02-21
发表刊物:
Molecules (Basel, Switzerland)
收录刊物:
SCIE、PubMed
文献类型:
J
卷号:
23
期号:
2
ISSN号:
1420-3049
关键字:
Lewis pair polymerization,block copolymers,brush copolymers,click reaction,organocatalytic ring-opening polymerization
摘要:
Lewis pair polymerization is a powerful method for preparing soluble polymers bearing pendant active vinyl groups by directly polymerizing dissymmetric divinyl polar monomers. Herein, we present a strategy for synthesizing block and brush copolymers via tandem Lewis pair polymerization of methacrylates, "thiol-ene" click reaction and organocatalytic ring-opening polymerization of lactide.
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