Asymmetric Copolymerization of CO2 with meso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity
发表时间：2019-03-09
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- 论文类型：
- 期刊论文
- 第一作者：
- Liu, Ye
- 通讯作者：
- Lu, XB (reprint author), Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China.
- 合写作者：
- Ren, Wei-Min,Liu, Jie,Lu, Xiao-Bing
- 发表时间：
- 2013-10-25
- 发表刊物：
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- 收录刊物：
- SCIE、EI、PubMed、Scopus
- 文献类型：
- J
- 卷号：
- 52
- 期号：
- 44
- 页面范围：
- 11594-11598
- ISSN号：
- 1433-7851
- 关键字：
- carbon dioxide; cobalt; copolymerization; meso-epoxides; polycarbonates
- 摘要：
- Unprecedented enantioselectivity and catalytic activity was observed in the asymmetric copolymerization of CO2 with meso-epoxides (including the less reactive cyclopentene oxide) mediated by the dinuclear Co(III) complex (S,S,S,S)-1 under mild conditions. The resultant copolymers possess more than 99 % carbonate linkages and a perfectly isotactic structure.Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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- 否
