点击次数：

论文类型：期刊论文

发表时间：2019-05-01

发表刊物：PROCESSES

收录刊物：SCIE

卷号：7

期号：5

ISSN号：2227-9717

关键字：hydrogen production; pyrolytic oil hydro-processing; process modeling; syngas

摘要：Hydrotreatment is an efficient method for pyrolytic oil upgrading; however, the trade-off between the operational cost on hydrogen consumption and process profit remains the major challenge for the process designs. In this study, an integrated process of steam methane reforming and pyrolytic oil hydrotreating with gas separation system was proposed conceptually. The integrated process utilized steam methane reformer to produce raw syngas without further water-gas-shifting; with the aid of a membrane unit, the hydrogen concentration in the syngas was adjusted, which substituted the water-gas-shift reactor and improved the performance of hydrotreater on both conversion and hydrogen consumption. A simulation framework for unit operations was developed for process designs through which the dissipated flow in the packed-bed reactor, along with membrane gas separation unit were modeled and calculated in the commercial process simulator. The evaluation results showed that, the proposed process could achieve 63.7% conversion with 2.0 wt% hydrogen consumption; the evaluations of economics showed that the proposed process could achieve 70% higher net profit compared to the conventional plant, indicating the potentials of the integrated pyrolytic oil upgrading process.