Indexed by:期刊论文
Date of Publication:2014-09-02
Journal:TETRAHEDRON
Included Journals:SCIE、Scopus
Volume:70
Issue:35
Page Number:5872-5877
ISSN No.:0040-4020
Key Words:ICT fluorophore; Skeletal characterization; Oxidative SNArH; 2D NMR; X-ray diffraction
Abstract:We have revisited the synthesis of a series of ICT fluorophores, which were reported to have a core structure of 8-oxo-8H-acenaphtho[1,2-b]pyrrol-9-carbonitrile. However, based on the 2D NMR and X-ray diffraction analysis, their core structure was corrected as 1-oxo-1H-phenalene-2,3-dicarbonitrile (1). Compound 1 shows a highly electron-deficient nature and can easily undergo oxidative SNArH reaction on the naphthyl ring to produce a series of novel ICT fluorophores. The regioselectivity of this substitution reaction was studied by introduction of representative nucleophiles. Moreover, due to the strong rigidity and efficient ICT nature, the obtained fluorescent dyes display very good spectroscopic properties even in an aqueous environment. (C) 2014 Elsevier Ltd. All rights reserved.
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Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Gender:Male
Alma Mater:Dalian University of Technology
Degree:Doctoral Degree
School/Department:State Key Laboratroy of Fine Chemicals
Discipline:Applied Chemistry. Fine Chemicals. Biochemical Engineering
Business Address:West Campus E-204
Contact Information:xiaoyi@dlut.edu.cn 0411-84986251
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