Indexed by:期刊论文

Date of Publication:2013-12-01

Journal:CHEMISTRY-AN ASIAN JOURNAL

Included Journals:SCIE、EI、Scopus

Volume:8

Issue:12

Page Number:3133-3141

ISSN No.:1861-4728

Key Words:BODIPY; dyes; energy transfer; laser chemistry; rhodamine

Abstract:This work deals with the synthesis and the photophysical and laser properties of new BODIPY-rhodamine cassettes. These dyads differ in their rigid and conjugated spacer group (phenyl or acetylenephenyl) and in their linking positions (meta or para). The photophysical properties of these cassettes are controlled by the formation/opening of the spirolactone ring, which, in turn, switches off/on an energy-transfer process between the chromophores. Herein, we thoroughly describe the influence of the attached spacer group, as well as the distance and orientation between the donor-acceptor pair, on the excitation energy transfer. The observed fast dynamics and efficiency suggest that the process mainly takes place through-bond, although the through-space mechanism also contributes to the whole process. As a result, efficient laser emission from the rhodamine is achieved upon excitation of the BODIPY, in particular for the cassette that contains an acetylenephenyl spacer group in a para disposition.